ondarvr
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I would think adding catalyst after thickening runs the risk of incomplete mixing.
There needs to some level of competency in one's ability to mix properly. If you do a piss poor job of mixing, then your results will reflect that. The world can't be made idiot proof.
After saying that, while it could be a real problem, it doesn’t often seem to create big problems in the real world. But it does happen.
Epoxy is different because of the mix ratios. Most of the time you wouldn't be able to get one part of it thick enough to be the right consistency after being combined together. So both parts would need to be thickened.
Since epoxy usage is miniscule compared to polyester and VE in much of the composites world, there just aren't as many marketed options for smallish users. And it's almost not profitable to produce putties for the polyester and VE segment because of high production costs and limited sales.