People used to seal boat decks with cotton, and build canoes that were sealed with cotton. I wonder if other fibers were used. If your friend doesn't want to use fiberglass, that might be an eco friendly alternative. Or not. One would have to compare the impact of industrial farming with that of fiberglass manufacturing. Cotton dust causes brown lung, though. In any case. One could look up how the fabric was used on decks and canoes.
In my experience, very light glass, maybe 30 gsm, with epoxy, followed by paint, can prevent plywood checking for many years. At least if you repair any dings before water can get in. The one exception was a plywood work bench I have, which was level, was outdoors in the weather, and had various objects sitting on it. Incidentally, 1/2" plywood vacuum bagged* either side of 2" XPS on makes a very sturdy, strong workbench surface that's still light enough to carry around.
Someone mentioned tar. We used to use pine tar, applied with a torch and a rag, as the base coat on the bottom of wood cross country skis. I wonder if it would bind plywood well enough to prevent checking and how well it would work as a primer or even a complete finish.
*Nothing high tech. Just Gorilla glue and a household vacuum.